Chris Evans
Role: Steve Rogers / Captain America
Samuel L. Jackson
Role: Nick Fury
Scarlett Johansson
Role: Natasha Romanoff / Black Widow
Robert Redford
Role: Alexander Pierce
Sebastian Stan
Role: Bucky Barnes / Winter Soldier
Anthony Mackie
Role: Sam Wilson / Falcon
Cobie Smulders
Role: Maria Hill
Frank Grillo
Role: Brock Rumlow
Maximiliano Hernández
Role: Jasper Sitwell
Emily VanCamp
Role: Kate / Agent 13
Hayley Atwell
Role: Peggy Carter
Toby Jones
Role: Dr. Arnim Zola
Stan Lee
Role: Smithsonian Guard
Callan Mulvey
Role: Jack Rollins
Jenny Agutter
Role: Councilwoman Hawley
Bernard White
Role: Councilman Singh
Alan Dale
Role: Councilman Rockwell
Chin Han
Role: Councilman Yen
Garry Shandling
Role: Senator Stern
Georges St-Pierre
Role: Georges Batroc
Salvator Xuereb
Role: French Pirate #1
Brian Duffy
Role: French Pirate #2
Zack Duhame
Role: Engine Pirate
Adetokumboh M'Cormack
Role: French Radio Pirate
Christopher George Sarris
Role: Skinny Steve
Aaron Himelstein
Role: Launch Tech #1
Allan Chanes
Role: Launch Tech #2
Christopher Markus
Role: SHIELD Interrogator #1
Stephen McFeely
Role: SHIELD Interrogator #2
Pat Healy
Role: Scientist #1
Ed Brubaker
Role: Scientist #2
D.C. Pierson
Role: Apple Employee
Danny Pudi
Role: Com Tech #1
Bernie Zilinskas
Role: Com Tech #2
Angela Russo-Otstot
Role: Garcia
Jon Sklaroff
Role: Charlie XO
Chad Todhunter
Role: Charlie Weapons Tech
Abigail Marlowe
Role: SHIELD Tech
Jeremy Maxwell
Role: Lead SHIELD Pilot
Emerson Brooks
Role: Senior SHIELD Agent
Evan Parke
Role: SHIELD Agent
Ricardo Chacon
Role: Strike SGT. #1
Griffin M. Allen
Role: Strike SGT. #2
Ann Russo
Role: Strike Agent
Joe Rosalina
Role: Strike Agent
Michael Debeljak
Role: Strike Agent
Eddie J. Fernandez
Role: Strike Agent
Jody Hart
Role: 25ᵗʰ Floor Strike Agent
Derek Hughes
Role: Human Resources Executive
Ethan Rains
Role: Lead EMT
Dominic Rains
Role: CIA Instructor
Charles Wittman
Role: Capitol Hill Police
Andy Martinez, Jr.
Role: Capitol Hill Police
Michael De Geus
Role: FBI Agent
Terence O'Rourke
Role: FBI Agent
Anne Grimenstein
Role: Committee Member
Dante Rosalina
Role: Little Boy in the Smithsonian
Robert Clotworthy
Role: Fury Car Voice (voice)
June Christopher
Role: SHIELD Computer (voice)
Gary Sinise
Role: The Smithsonian Narrator (voice)
Henry Goodman
Role: Dr. List (uncredited)
Dean Barlage
Role: SHIELD Agent (uncredited)
Joel Thingvall
Role: Museum Visitor (uncredited)
Thomas Kretschmann
Role: Baron Wolfgang von Strucker (uncredited)
Elizabeth Olsen
Role: Wanda Maximoff / Scarlet Witch (uncredited)
Nestor Serrano
Role: Committee General (uncredited)
Aaron Taylor-Johnson
Role: Pietro Maximoff / Quicksilver (uncredited)
Joss Whedon
Role: Man on Escalator in Museum (uncredited)
James Lewis
Role: Smithsonian Museum Visitor